<> "The repository administrator has not yet configured an RDF license."^^ . <> . . "Electron Transfer through Thin Organic Films and Highly Curved Donor-Bridge-Acceptor Molecules."^^ . "Electron-transfer rate constants were measured for a variety of molecular systems. Therate constant was found to depend upon the nature of the medium between the electron donor andacceptor moieties. Using a superexchange model to calculate the electronic coupling betweendonor and acceptor, the effect of orbital energetics was studied. For photoinduced electrontransfer, aromatic moieties with large electron affinities promote large electronic couplingmagnitudes. In the electrochemical systems studied involving a gold electrode and animmobilized ferrocene tethered alkanethiol, alkane chains were found to be more efficient atpromoting electron transfer than chains incorporating ether linkages. This indicates a dominanthole-transfer mechanism for the electrochemical systems. Chemical modification of adjacentdiluent alkanethiols also resulted in alteration of the rate constant. This suggests intermolecularinteractions are important in electron transfer in these systems."^^ . "2003-03-10" . . . . . . . . "Andrew Michael"^^ . "Napper"^^ . "Andrew Michael Napper"^^ . . . . . . "Electron Transfer through Thin Organic Films and Highly Curved Donor-Bridge-Acceptor Molecules. (PDF)"^^ . . . . . . "thesis2.pdf"^^ . . . "Electron Transfer through Thin Organic Films and Highly Curved Donor-Bridge-Acceptor Molecules. (Indexer Terms)"^^ . . . . . . "indexcodes.txt"^^ . . . "Electron Transfer through Thin Organic Films and Highly Curved Donor-Bridge-Acceptor Molecules. (Other)"^^ . . . . . . "lightbox.jpg"^^ . . . "Electron Transfer through Thin Organic Films and Highly Curved Donor-Bridge-Acceptor Molecules. (Other)"^^ . . . . . . "preview.jpg"^^ . . . "Electron Transfer through Thin Organic Films and Highly Curved Donor-Bridge-Acceptor Molecules. (Other)"^^ . . . . . . "medium.jpg"^^ . . . "Electron Transfer through Thin Organic Films and Highly Curved Donor-Bridge-Acceptor Molecules. (Other)"^^ . . . . . . "small.jpg"^^ . . "HTML Summary of #9329 \n\nElectron Transfer through Thin Organic Films and Highly Curved Donor-Bridge-Acceptor Molecules.\n\n" . "text/html" . .