relation: http://d-scholarship-dev.library.pitt.edu/27585/
title: Insertion of reactive rhodium carbenes into boron-hydrogen bonds of stable N-heterocyclic carbene boranes
creator: Li, X
creator: Curran, DP
description: Readily available rhodium(II) salts catalyze reactions between NHC-boranes (NHC-BH3) and diazocarbonyl compounds (N2CRCOR′). Stable α-NHC-boryl carbonyl compounds (NHC-BH2-CHRCOR′) are isolated in good yields. The reaction is a reliable way to make boron-carbon bonds with good tolerance for variation in both the NHC-borane and diazocarbonyl components. It presumably occurs by insertion of a transient rhodium carbene into a boron-hydrogen bond of the NHC-borane. Competitive experiments show that a typical NHC-borane is highly reactive toward rhodium carbenes. © 2013 American Chemical Society.
date: 2013-08-14
type: Article
type: PeerReviewed
format: text/plain
language: en
rights: attached
identifier: http://d-scholarship-dev.library.pitt.edu/27585/1/licence.txt
identifier:   Li, X and Curran, DP  (2013) Insertion of reactive rhodium carbenes into boron-hydrogen bonds of stable N-heterocyclic carbene boranes.  Journal of the American Chemical Society, 135 (32).  12076 - 12081.  ISSN 0002-7863     
relation: 10.1021/ja4056245