%0 Journal Article %@ 0002-7863 %A Prokofjevs, A %A Kampf, JW %A Solovyev, A %A Curran, DP %A Vedejs, E %D 2013 %F pittir:27581 %J Journal of the American Chemical Society %N 42 %P 15686 - 15689 %T Weakly stabilized primary borenium cations and their dicationic dimers %U http://d-scholarship-dev.library.pitt.edu/27581/ %V 135 %X Hydride abstraction from monocationic hydride bridged salts [H(H 2B-L)2]+ [B(C6F5) 4]̄ (L = Lewis base) generates an observable primary borenium cation for L = iPr2NEt, but with L = Me3N, Me 2NPr, or several N-heterocyclic carbenes, highly reactive dicationic dimers are formed. © 2013 American Chemical Society.