TY - JOUR ID - pittir22506 UR - http://d-scholarship-dev.library.pitt.edu/22506/ IS - 17 A1 - Curran, DP A1 - Luo, Z A1 - Degenkolb, P Y1 - 1998/09/08/ N2 - A new generation of propylene-spaced fluorous allyltin reagents [(Rf(CH2)3)3SnCH2CH=CH2] is described. These succeed in radical allylations where their lower homologs (ethylene-spaced) fail, and they provide improved performance in transition metal catalyzed allylations. The reagents and byproducts are readily separated by simple fluorous-organic liquid-liquid or solid-liquid extractions. JF - Bioorganic and Medicinal Chemistry Letters VL - 8 SN - 0960-894X TI - 'Propylene spaced' allyl tin reagents: A new class of fluorous tin reagents for allylations under radical and metal-catalyzed conditions SP - 2403 AV - public EP - 2408 ER -