<> "The repository administrator has not yet configured an RDF license."^^ . <> . . . "Toward the total synthesis of lophotoxin - New methodologies and synthetic strategies"^^ . "Our recent progress toward the synthesis of the furanocembranolide lophotoxin (1) is disclosed. Strategies for the stereoselective incorporation of the C13 stereocenter by a catalytic desymmetrization of a cyclic meso-anhydride, as well as a novel 1,6-addition reaction of organocuprates to unsaturated [1,3]dioxin-4-ones are discussed. Preliminary results on the development of a rhodium-catalyzed asymmetric 1,6-addition reaction are also mentioned. Finally, modifications of a previously reported transition-metal- catalyzed cyclization reaction involving α-propargyl β-keto esters allow furan ring formation either under thermal conditions or by microwave irradiation. © 2006 NRC."^^ . "2006-10-01" . . "84" . "10" . . "Canadian Journal of Chemistry"^^ . . . "00084042" . . . . . . . . . . "M"^^ . "Grenon"^^ . "M Grenon"^^ . . "P"^^ . "Wipf"^^ . "P Wipf"^^ . . . . . . "Toward the total synthesis of lophotoxin - New methodologies and synthetic strategies (Plain Text)"^^ . . . "licence.txt"^^ . . . "Toward the total synthesis of lophotoxin - New methodologies and synthetic strategies (Other)"^^ . . . . . . "indexcodes.txt"^^ . . "HTML Summary of #22504 \n\nToward the total synthesis of lophotoxin - New methodologies and synthetic strategies\n\n" . "text/html" . .