relation: http://d-scholarship-dev.library.pitt.edu/22459/
title: Radical carbonylations with fluorous allyltin reagents
creator: Ryu, I
creator: Niguma, T
creator: Minakata, S
creator: Komatsu, M
creator: Luo, Z
creator: Curran, DP
description: 'Propylene-spaced' fluorous allyltin reagents 2a and 2b were tested as mediators of radical carbonylations and found to be useful for four-component coupling reactions comprising RX 3, CO, alkenes, and 2 leading to β- functionalized β-allylated ketones 5. The biphasic workup (acetonitrile/FC- 72) was successfully carried out to separate 5 from tin compounds. Competition experiments suggested a modest reactivity of 2a for the chain propagation involving S(H)2' step in comparison with conventional allyltributyltin.
date: 1999-03-19
type: Article
type: PeerReviewed
format: text/plain
language: en
rights: attached
identifier: http://d-scholarship-dev.library.pitt.edu/22459/1/licence.txt
identifier:   Ryu, I and Niguma, T and Minakata, S and Komatsu, M and Luo, Z and Curran, DP  (1999) Radical carbonylations with fluorous allyltin reagents.  Tetrahedron Letters, 40 (12).  2367 - 2370.  ISSN 0040-4039     
relation: 10.1016/S0040-4039(99)00188-4