@unpublished{pittir22382,
           month = {September},
           title = {SIGMATROPIC REARRANGEMENTS OF DIVINYLCYCLOPROPANES AND CYCLIZATIONS INVOLVING {\ensuremath{\beta}}-ELIMINATION OF SULFONYL RADICALS},
          author = {Everett Ben Hay},
            year = {2014},
        keywords = {Cyclopropane, Sigmatropic Rearrangement, Radical Cyclization, Sulfonyl Radical},
             url = {http://d-scholarship-dev.library.pitt.edu/22382/},
        abstract = {The first chapter of this dissertation describes the synthesis and reactions of a family of 1,1-divinylcyclopropanes, including the discovery and studies of several sigmatropic rearrangement cascades. Also discussed is the radical [3+2] cyclization of 1,1-divinylcyclopropanes with the potential for memory of chirality.
The second chapter deals with the elimination of sulfonyl radicals during radical cyclizations of ene-sulfonamides. A family of polycyclic imines and a family of oxindole products were synthesized from polycyclic ene-sulfonamide precursors.}
}