@article{pittir22250,
          volume = {14},
          number = {22},
           month = {November},
          author = {P Wipf and JG Pierce and X Wang},
           title = {Investigation of ligand loading and asymmetric amplification in CHAOx-catalyzed asymmetric diethylzinc additions},
         journal = {Tetrahedron Asymmetry},
           pages = {3605 -- 3611},
            year = {2003},
             url = {http://d-scholarship-dev.library.pitt.edu/22250/},
        abstract = {The recently developed (cyclohexylsulfonylamino)oxazoline (CHAOx) ligand was found to provide high ee's and consistent reaction rates in the asymmetric diethylzinc addition to benzaldehyde over a remarkably large loading range of 0.05-10 mol\%. Turnover numbers of 1000-2000 can be explained by the absence of a nonlinear effect and the formation of a catalytically active monomer complex. Substituents at the nitrogen donor atoms of the bidentate ligand prevent zinc-complex dimerization. {\copyright} 2003 Elsevier Ltd. All rights reserved.}
}