<> "The repository administrator has not yet configured an RDF license."^^ . <> . . . "Synthesis and chemical diversity analysis of bicyclo[3.3.1]non-3-en-2-ones"^^ . "Functionalized bicyclo[3.3.1]non-3-en-2-ones are obtained from commercially available phenols by a hypervalent iodine oxidation, enone epoxidation, epoxide thiolysis, and intramolecular aldol reaction sequence. Reaction optimization studies identified room temperature as well as microwave-mediated procedures, providing moderate to good yields (57-88%) in the thiophenol-mediated epoxide opening and intramolecular aldol reaction. In addition, the isolation of a key intermediate and in situ NMR studies supported the mechanistic hypothesis. The bicyclic ring products occupy novel chemical space according to ChemGPS and Chemaxon chemical diversity and cheminformatics analyses. © 2010 Elsevier Ltd."^^ . "2010-07-31" . . "66" . "31" . . "Tetrahedron"^^ . . . "00404020" . . . . . . . . . . . . . . . . . . . . . . "AM"^^ . "Virshup"^^ . "AM Virshup"^^ . . "JT"^^ . "Hammill"^^ . "JT Hammill"^^ . . "W"^^ . "Yang"^^ . "W Yang"^^ . . "DN"^^ . "Beratan"^^ . "DN Beratan"^^ . . "J"^^ . "Contreras-García"^^ . "J Contreras-García"^^ . . "P"^^ . "Wipf"^^ . "P Wipf"^^ . . . . . . "Synthesis and chemical diversity analysis of bicyclo[3.3.1]non-3-en-2-ones (Plain Text)"^^ . . . "licence.txt"^^ . . . "Synthesis and chemical diversity analysis of bicyclo[3.3.1]non-3-en-2-ones (Other)"^^ . . . . . . "indexcodes.txt"^^ . . "HTML Summary of #22231 \n\nSynthesis and chemical diversity analysis of bicyclo[3.3.1]non-3-en-2-ones\n\n" . "text/html" . .