TY - JOUR ID - pittir20633 UR - http://d-scholarship-dev.library.pitt.edu/20633/ IS - 1 A1 - Nakamura, Y A1 - Takeuchi, S A1 - Ohgo, Y A1 - Curran, DP Y1 - 2000/01/01/ N2 - Fluorous chiral BINOL ((R)-FBINOL) was prepared by short reaction steps in good overall yield and was applied to the catalytic asymmetric alkylation in a toluene and FC-72 biphase system. The (R)-FBINOL-Ti complex in the FC-72 phase was consecutively reused in the biphase system and the enantioselectivity was still higher than 80% ee at the 5th reaction. JF - Tetrahedron Letters VL - 41 SN - 0040-4039 TI - Asymmetric alkylation of aromatic aldehydes with diethylzinc catalyzed by a fluorous BINOL-Ti complex in an organic and fluorous biphase system SP - 57 AV - public EP - 60 ER -