relation: http://d-scholarship-dev.library.pitt.edu/20633/
title: Asymmetric alkylation of aromatic aldehydes with diethylzinc catalyzed by a fluorous BINOL-Ti complex in an organic and fluorous biphase system
creator: Nakamura, Y
creator: Takeuchi, S
creator: Ohgo, Y
creator: Curran, DP
description: Fluorous chiral BINOL ((R)-FBINOL) was prepared by short reaction steps in good overall yield and was applied to the catalytic asymmetric alkylation in a toluene and FC-72 biphase system. The (R)-FBINOL-Ti complex in the FC-72 phase was consecutively reused in the biphase system and the enantioselectivity was still higher than 80% ee at the 5th reaction.
date: 2000-01-01
type: Article
type: PeerReviewed
format: text/plain
language: en
rights: attached
identifier: http://d-scholarship-dev.library.pitt.edu/20633/1/licence.txt
identifier:   Nakamura, Y and Takeuchi, S and Ohgo, Y and Curran, DP  (2000) Asymmetric alkylation of aromatic aldehydes with diethylzinc catalyzed by a fluorous BINOL-Ti complex in an organic and fluorous biphase system.  Tetrahedron Letters, 41 (1).  57 - 60.  ISSN 0040-4039     
relation: 10.1016/S0040-4039(99)01999-1