@article{pittir20633, volume = {41}, number = {1}, month = {January}, author = {Y Nakamura and S Takeuchi and Y Ohgo and DP Curran}, title = {Asymmetric alkylation of aromatic aldehydes with diethylzinc catalyzed by a fluorous BINOL-Ti complex in an organic and fluorous biphase system}, journal = {Tetrahedron Letters}, pages = {57 -- 60}, year = {2000}, url = {http://d-scholarship-dev.library.pitt.edu/20633/}, abstract = {Fluorous chiral BINOL ((R)-FBINOL) was prepared by short reaction steps in good overall yield and was applied to the catalytic asymmetric alkylation in a toluene and FC-72 biphase system. The (R)-FBINOL-Ti complex in the FC-72 phase was consecutively reused in the biphase system and the enantioselectivity was still higher than 80\% ee at the 5th reaction.} }