%0 Journal Article %@ 0040-4020 %A Nakamura, Y %A Takeuchi, S %A Ohgo, Y %A Curran, DP %D 2000 %F pittir:20618 %J Tetrahedron %N 3 %P 351 - 356 %T Preparation of a fluorous chiral BINOL derivative and application to an asymmetric protonation reaction %U http://d-scholarship-dev.library.pitt.edu/20618/ %V 56 %X Fluorous Chiral Proton Source (R,S)-FDHPEB resulted in a higher enantioselectivity (95% ee) than that of the original nonfluorous (R,S)-DHPEB (87% ee) in an enantioselective protonation of a samarium enolate. (R,S)- FDHPEB was easily recovered by a simple filtration through a fluorous reverse phase silica gel and was recyclable. (C) 2000 Elsevier Science Ltd.