relation: http://d-scholarship-dev.library.pitt.edu/20560/
title: Tris (perfluoroalkylethyl)silyl alkyl amines as calibration standards for electron ionization mass spectrometry in the mass range of 100-3000 Da
creator: Fishman, VN
creator: Linclau, B
creator: Curran, DP
creator: Somayajula, KV
description: A new fluorinated compound mixture has been developed for the calibration of the double focusing mass spectrometer in the mass range of 100-3000 Da in the positive electron ionization (EI) mode. Current calibration standards for EI have either limited mass range [perfluorotributylamine (PFTBA), perfluorokerosene (PFK), s-triazines (TRIS)] or poor peak intensities with significant chemical background in the instrument for several days (perfluoroalkyl phosphazine). The newly synthesized fluorinated silyl alkyl amines mixture is proposed as a reference/calibration standard for EI-MS. This standard produced abundant parent and fragment ions across the entire mass range without any memory effect. Copyright © 2001 American Society for Mass Spectrometry.
date: 2001-12-01
type: Article
type: PeerReviewed
format: text/plain
language: en
rights: attached
identifier: http://d-scholarship-dev.library.pitt.edu/20560/1/licence.txt
identifier:   Fishman, VN and Linclau, B and Curran, DP and Somayajula, KV  (2001) Tris (perfluoroalkylethyl)silyl alkyl amines as calibration standards for electron ionization mass spectrometry in the mass range of 100-3000 Da.  Journal of the American Society for Mass Spectrometry, 12 (9).  1050 - 1054.  ISSN 1044-0305     
relation: 10.1016/S1044-0305(01)00284-7