TY - JOUR ID - pittir20540 UR - http://d-scholarship-dev.library.pitt.edu/20540/ IS - SPEC. A1 - Curran, DP A1 - Gualtieri, G Y1 - 2001/01/01/ N2 - Two members of a new class of dithiogermanium hydrides have been prepared in racemic and enantiopure form. Reaction of 2,2?-dithiobinap and 3,3?-bis-trimethylsilyl-2,2?-dithiobinap with tBuGeCl3 followed by reduction provides the corresponding germanium hydrides. Hydrogermylation of methyl methacrylate occurs with low selectivity (<3/1) for the former substrate but high selectivity (>10/1) for the latter. JF - Synlett SN - 0936-5214 TI - Synthesis and asymmetric hydrogermylation reactions of dithiogermanium hydrides derived from C2-symmetric dithiols SP - 1038 AV - public EP - 1041 ER -