eprintid: 20537 rev_number: 19 userid: 1418 dir: disk0/00/02/05/37 datestamp: 2014-02-13 19:28:24 lastmod: 2020-07-19 11:56:03 status_changed: 2014-02-13 19:28:24 type: article metadata_visibility: show item_issues_count: 0 eprint_status: archive creators_name: Curran, DP creators_email: curran@pitt.edu creators_id: CURRAN title: Fluorous reverse phase silica gel. A new tool for preparative separations in synthetic organic and organofluorine chemistry ispublished: pub divisions: sch_as_chemistry full_text_status: public abstract: Fluorous reverse phase silica gel, or silica gel with a fluorocarbon bonded phase, can be readily prepared by standard techniques, but shows unusual separation features. This silica gel separates primarily by fluorine content. Uses of fluorous reverse phase silica gel in both synthetic organic chemistry and organofluorine chemistry are introduced. Solid phase extraction can be used to separate fluorous or fluorous-tagged compounds from organic compounds. Fluorous chromatography can be used to purify mixtures of compounds with differing fluorine content as well as for "demixing" in the new technique of fluorous mixture synthesis. date: 2001-01-01 date_type: published publication: Synlett number: 9 pagerange: 1488 - 1496 refereed: TRUE issn: 0936-5214 id_number: 10.1055/s-2001-16800 citation: Curran, DP (2001) Fluorous reverse phase silica gel. A new tool for preparative separations in synthetic organic and organofluorine chemistry. Synlett (9). 1488 - 1496. ISSN 0936-5214 document_url: http://d-scholarship-dev.library.pitt.edu/20537/1/licence.txt