eprintid: 20483
rev_number: 16
userid: 1419
dir: disk0/00/02/04/83
datestamp: 2014-02-13 18:57:23
lastmod: 2019-02-02 15:57:14
status_changed: 2014-02-13 18:57:23
type: article
metadata_visibility: show
item_issues_count: 0
eprint_status: archive
creators_name: Wipf, P
creators_name: Ribe, S
creators_email: pwipf@pitt.edu
creators_email: 
creators_id: PWIPF
creators_id: 
title: Water-Accelerated Tandem Claisen Rearrangement-Catalytic Asymmetric Carboalumination
ispublished: pub
divisions: sch_as_chemistry
full_text_status: public
abstract: matrix presented The addition of stoichiometric quantities of water accelerates both the trimethylaluminum-mediated aromatic Claisen reaction and the chiral zirconocene-catalyzed asymmetric carboalumination of terminal alkenes. The two reactions occur in a tandem sequence resulting in the selective formation of two new C-C and one C-O bond after oxidative quench of the intermediate trialkylalane.
date: 2001-05-17
date_type: published
publication: Organic Letters
volume: 3
number: 10
pagerange: 1503 - 1505
refereed: TRUE
issn: 1523-7060
id_number: 10.1021/ol015816z
pmid: 11388852
citation:   Wipf, P and Ribe, S  (2001) Water-Accelerated Tandem Claisen Rearrangement-Catalytic Asymmetric Carboalumination.  Organic Letters, 3 (10).  1503 - 1505.  ISSN 1523-7060     
document_url: http://d-scholarship-dev.library.pitt.edu/20483/1/licence.txt