relation: http://d-scholarship-dev.library.pitt.edu/20481/
title: Tandem zirconocene homologation-aldimine allylation
creator: Wipf, P
creator: Kendall, C
description: (Equation presented) Hydrozirconation of internal and terminal alkynes followed by in situ transmetalation to dimethylzinc and treatment with diiodomethane leads to chain extended allylic organometallics. Addition to N-phosphinoyl or N-sulfonyl aldimines provides homoallylic amines in 48-87% yield and 3:2 to >20:1 diastereomeric ratios favoring anti-products.
date: 2001-08-23
type: Article
type: PeerReviewed
format: text/plain
language: en
rights: attached
identifier: http://d-scholarship-dev.library.pitt.edu/20481/1/licence.txt
identifier:   Wipf, P and Kendall, C  (2001) Tandem zirconocene homologation-aldimine allylation.  Organic Letters, 3 (17).  2773 - 2776.  ISSN 1523-7060     
relation: 10.1021/ol0163880