%A H Nakamura
%A T Usui
%A H Kuroda
%A I Ryu
%A H Matsubara
%A S Yasuda
%A DP Curran
%J Organic Letters
%T Fluorous solvent as a new phase-screen medium between reagents and reactants in the bromination and chlorination of alcohols
%X (Matrix presented) A perfluorohexane layer regulates the rate of reagent transport in the bromination and chlorination of alcohols. A fluorous triphasic U-tube method is effective for lighter reagents; the thionyl chloride layer (yellow) vanishes, and the chlorides are obtained from the right top organic layer in the chlorination of alcohols.
%N 8
%P 1167 - 1169
%V 5
%D 2003
%R 10.1021/ol034060w
%L pittir20464