eprintid: 20456
rev_number: 17
userid: 1419
dir: disk0/00/02/04/56
datestamp: 2014-02-12 23:42:11
lastmod: 2019-02-05 16:55:09
status_changed: 2014-02-12 23:42:11
type: article
metadata_visibility: show
item_issues_count: 0
eprint_status: archive
creators_name: Wipf, P
creators_name: Wang, X
creators_email: pwipf@pitt.edu
creators_email: 
creators_id: PWIPF
creators_id: 
title: A New Ligand Scaffold for Catalytic Asymmetric Alkylzinc Additions to Aldehydes
ispublished: pub
divisions: sch_as_chemistry
full_text_status: public
abstract: matrix presented 1,3-Azole derivatives of 2-aminocyclohexanecarboxylic acid represent a new class of bidentate ligands for metal-mediated catalytic asymmetric synthesis. N-[2-(4-Isopropyl-4,5-dihydrooxazol-2-yl)cyclohexyl]methanesulfonamide (6) is particularly well suited for the addition of alkylzinc reagents to aliphatic aldehydes in high enantiomeric excess.
date: 2002-04-04
date_type: published
publication: Organic Letters
volume: 4
number: 7
pagerange: 1197 - 1199
refereed: TRUE
issn: 1523-7060
id_number: 10.1021/ol025600c
other_id: 10.1021/ol025600c
pmid: 11922817
citation:   Wipf, P and Wang, X  (2002) A New Ligand Scaffold for Catalytic Asymmetric Alkylzinc Additions to Aldehydes.  Organic Letters, 4 (7).  1197 - 1199.  ISSN 1523-7060     
document_url: http://d-scholarship-dev.library.pitt.edu/20456/1/licence.txt