eprintid: 19981 rev_number: 22 userid: 1419 dir: disk0/00/01/99/81 datestamp: 2013-11-12 17:17:27 lastmod: 2021-06-12 22:55:54 status_changed: 2013-11-12 17:17:27 type: article metadata_visibility: show item_issues_count: 0 eprint_status: archive creators_name: Moss, RA creators_name: Fu, X creators_name: Tian, J creators_name: Sauers, R creators_name: Wipf, P creators_email: creators_email: creators_email: creators_email: creators_email: pwipf@pitt.edu creators_id: creators_id: creators_id: creators_id: creators_id: PWIPF title: Stereochemistry of oxachlorocarbene SNi reactions ispublished: pub divisions: sch_as_chemistry full_text_status: public abstract: (Chemical Equation Presented) 3-Nortricyclyloxychlorocarbene and trans-4-methylcyclohexyloxychlorocarbene both fragment in hydrocarbon solvents with extensive loss of stereochemical integrity to the corresponding chlorides via competitive and nearly isoenergetic SNi-like transition states. © 2005 American Chemical Society. date: 2005-03-31 date_type: published publication: Organic Letters volume: 7 number: 7 pagerange: 1371 - 1374 refereed: TRUE issn: 1523-7060 id_number: 10.1021/ol050185k pmid: 15787509 citation: Moss, RA and Fu, X and Tian, J and Sauers, R and Wipf, P (2005) Stereochemistry of oxachlorocarbene SNi reactions. Organic Letters, 7 (7). 1371 - 1374. ISSN 1523-7060 document_url: http://d-scholarship-dev.library.pitt.edu/19981/1/licence.txt