eprintid: 19909 rev_number: 16 userid: 1418 dir: disk0/00/01/99/09 datestamp: 2013-10-30 16:59:59 lastmod: 2019-02-02 15:58:29 status_changed: 2013-10-30 16:59:59 type: article metadata_visibility: show item_issues_count: 0 eprint_status: archive creators_name: Curran, DP creators_name: Werner, S creators_email: curran@pitt.edu creators_email: creators_id: CURRAN creators_id: title: Extractive phase vanishing reactions with dichloromethane, perfluorohexanes, and dibromoethane: Slow addition in a test tube ispublished: pub divisions: sch_as_chemistry full_text_status: public abstract: (Equation presented) Partition coefficient measurements and experiments with a dye show that a new fluorous "phase vanishing reaction" described by Jana and Verkade occurs by an extractive mechanism. This mechanism is contrasted with the original diffusive phase-vanishing reactions introduced by Ryu and co-workers. date: 2004-03-18 date_type: published publication: Organic Letters volume: 6 number: 6 pagerange: 1021 - 1024 refereed: TRUE issn: 1523-7060 id_number: 10.1021/ol0499248 pmid: 15012090 mesh_headings: Azo Compounds mesh_headings: Countercurrent Distribution mesh_headings: Diffusion mesh_headings: Ethylene Dibromide--chemistry mesh_headings: Fluorocarbons--chemistry mesh_headings: Indicators and Reagents mesh_headings: Methylene Chloride--chemistry mesh_headings: Solvents--chemistry mesh_headings: Time Factors chemical_names: Azo Compounds chemical_names: Fluorocarbons chemical_names: Indicators and Reagents chemical_names: Solvents chemical_names: Ethylene Dibromide chemical_names: fat red 7B chemical_names: Methylene Chloride chemical_names: perflexane citation: Curran, DP and Werner, S (2004) Extractive phase vanishing reactions with dichloromethane, perfluorohexanes, and dibromoethane: Slow addition in a test tube. Organic Letters, 6 (6). 1021 - 1024. ISSN 1523-7060 document_url: http://d-scholarship-dev.library.pitt.edu/19909/1/licence.txt