TY  - JOUR
ID  - pittir19899
UR  - http://d-scholarship-dev.library.pitt.edu/19899/
IS  - 20
A1  - Curran, DP
A1  - Chen, CHT
A1  - Geib, SJ
A1  - Lapierre, AJB
Y1  - 2004/05/10/
N2  - Radical cyclizations of enantiomerically enriched N-allyl-o-iodoanilides provide N-acyl-3-alkyl-2,3-dihydroindoles in good yields and with good to excellent levels of chirality transfer from the N-Ar axis to the new stereocenter. In competitive cyclizations of N-acryloyl-N-allyl-o-iodoanilides, the addition of an o-methyl group reverses the regioselectivity of the radical cyclization from the acryloyl group to the allyl group. Approximate rate constants for representative radical cyclizations have been measured to provide insight into the origin of these observations. © 2004 Elsevier Ltd. All rights reserved.
JF  - Tetrahedron
VL  - 60
SN  - 0040-4020
TI  - Asymmetric radical cyclization reactions of axially chiral N-allyl-o-iodoanilides to form enantioenriched N-acyl dihydroindoles
SP  - 4413 
AV  - public
EP  -  4424
ER  -