TY  - JOUR
ID  - pittir19722
UR  - http://d-scholarship-dev.library.pitt.edu/19722/
IS  - 33
A1  - Dandapani, S
A1  - Jeske, M
A1  - Curran, DP
Y1  - 2004/08/17/
N2  - All 16 stereoisomers of the sex pheromone of pine sawfly (3,7,11-trimethylundecanol propanoate ester) have been synthesized on a 10- to 20-mg scale by a split-parallel fluorous mixture-synthesis approach. Spectral data obtained for all 32 compounds (16 alcohols and the corresponding propionates) matched well with published data, thereby validating the fluorous-tag encoding of diastereoisomers. This fluorous-tag encoding method is recommended for the efficient synthesis of multiple stereoisomers for spectroscopic studies, biological tests, or other structure-function relationships.
JF  - Proceedings of the National Academy of Sciences of the United States of America
VL  - 101
SN  - 0027-8424
TI  - Stereoisomer libraries: Total synthesis of all 16 stereoisomers of the pine sawfly sex pheromone by a fluorous mixture-synthesis approach
SP  - 12008 
AV  - public
EP  -  12012
ER  -