eprintid: 19460 rev_number: 16 userid: 1419 dir: disk0/00/01/94/60 datestamp: 2013-08-07 15:43:45 lastmod: 2019-02-02 15:57:00 status_changed: 2013-08-07 15:43:45 type: article metadata_visibility: show item_issues_count: 0 eprint_status: archive creators_name: Mukhopadhyay, P creators_name: Zuber, G creators_name: Wipf, P creators_name: Beratan, DN creators_email: creators_email: creators_email: pwipf@pitt.edu creators_email: creators_id: creators_id: creators_id: PWIPF creators_id: title: Contribution of a solute's chiral solvent imprint to optical rotation ispublished: pub divisions: sch_as_chemistry full_text_status: public abstract: Solvent or solute dissymmetry? The dissymmetric ordering of solvent molecules around the chiral solute (see picture) contributes to the chiroptical signature. Indeed, the solvent can dominate the chiroptical response, as shown for (S)-methyloxirane in benzene. (Figure Presented). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA. date: 2007-09-05 date_type: published publication: Angewandte Chemie - International Edition volume: 46 number: 34 pagerange: 6450 - 6452 refereed: TRUE issn: 1433-7851 id_number: 10.1002/anie.200702273 pmid: 17645276 citation: Mukhopadhyay, P and Zuber, G and Wipf, P and Beratan, DN (2007) Contribution of a solute's chiral solvent imprint to optical rotation. Angewandte Chemie - International Edition, 46 (34). 6450 - 6452. ISSN 1433-7851 document_url: http://d-scholarship-dev.library.pitt.edu/19460/1/licence.txt