@article{pittir19309, volume = {130}, number = {22}, month = {June}, author = {MAA Walczak and P Wipf}, title = {Rhodium(I)-catalyzed cycloisomerizations of bicyclobutanes}, journal = {Journal of the American Chemical Society}, pages = {6924 -- 6925}, year = {2008}, url = {http://d-scholarship-dev.library.pitt.edu/19309/}, abstract = {The selection of rhodium precatalyst and phosphine ligand determines the course of the cycloisomerization of N-allylated bicyclo[1.1.0]butylalkylamines. Cyclopropane-fused pyrrolidines and azepines are obtained with high levels of stereo- and regiocontrol. Novel azatricyclo[6.1.0.01,5]nonanes are the result of a tandem cycloisomerization-ring closing metathesis sequence. Allylic ethers lead to furans and oxepanes. Copyright {\copyright} 2008 American Chemical Society.} }