TY  - JOUR
ID  - pittir18883
UR  - http://d-scholarship-dev.library.pitt.edu/18883/
A1  - Curran, DP
A1  - Turner, TR
Y1  - 2006/05/25/
N2  - The generation of ?-acyloxy and ?-alkoxycarbonyloxy radicals under reductive conditions in fragmentable probe experiments does not provide unequivocal evidence for the fragmentation of such radicals to give ketones and acyl or alkoxycarbonyl radicals. Instead, standard reduction predominates, even at low tin hydride concentrations. Some ketone product is formed in the ?-acyloxy substrate at low concentrations, but it is unclear whether this product arises through a slow radical fragmentation process or an inefficient, chain-breaking oxidative process. © 2006 Curran and Turner; licensee Beilstein-Institut.
JF  - Beilstein Journal of Organic Chemistry
VL  - 2
SN  - 1860-5397
TI  - Do alpha-acyloxy and alpha-alkoxycarbonyloxy radicals fragment to form acyl and alkoxycarbonyl radicals?
AV  - public
ER  -