TY - JOUR ID - pittir18743 UR - http://d-scholarship-dev.library.pitt.edu/18743/ IS - 10 A1 - Hoye, AT A1 - Wipf, P Y1 - 2011/05/20/ N2 - A convergent route featuring [3,3]-sigmatropic rearrangements of a linchpin azepinopyrrolidine served to install two of the four contiguous stereocenters present in the tricyclic Stemona alkaloids sessilifoliamide and stemoamide. In addition to the first total synthesis of (-)-sessilifoliamide C, a potential biosynthetic relationship between the sessilifoliamides and previously reported Stemona alkaloids is presented. © 2011 American Chemical Society. JF - Organic Letters VL - 13 SN - 1523-7060 TI - Total synthesis of (-)-sessilifoliamide C and (-)-8-epi-stemoamide SP - 2634 AV - public EP - 2637 ER -