relation: http://d-scholarship-dev.library.pitt.edu/18700/
title: Radical additions of aryl iodides to arenes are facilitated by oxidative rearomatization with dioxygen
creator: Curran, DP
creator: Keller, AI
description: Inter- and intramolecular additions of aryl radicals derived from aryl iodides to arenes are promoted by tris(trimethylsilyl)silane and occur under exceptionally mild conditions (15-30 min at 25 °C) in nondegassed benzene. A chain mechanism involving reaction of the intermediate cyclohexadienyl radical with oxygen to directly generate the aromatized product and the hydroperoxy radical is proposed. Copyright © 2006 American Chemical Society.
date: 2006-10-25
type: Article
type: PeerReviewed
format: text/plain
language: en
rights: attached
identifier: http://d-scholarship-dev.library.pitt.edu/18700/1/licence.txt
identifier:   Curran, DP and Keller, AI  (2006) Radical additions of aryl iodides to arenes are facilitated by oxidative rearomatization with dioxygen.  Journal of the American Chemical Society, 128 (42).  13706 - 13707.  ISSN 0002-7863     
relation: 10.1021/ja066077q