TY  - JOUR
ID  - pittir18362
UR  - http://d-scholarship-dev.library.pitt.edu/18362/
IS  - 39
A1  - Chu, Q
A1  - Yu, MS
A1  - Curran, DP
Y1  - 2007/09/24/
N2  - Miscibility tests between 60 pairs of fluorous and organic solvents have been performed, and a number of biphasic systems based on hydrofluoroether solvents have been identified. Mutual solubilities of a series of fluorous and organic solvents have been measured to ascertain the compositions of the biphasic systems. A qualitative solvent tuning strategy based on solvent polarity and fluorophilicity/phobicity is introduced. Solvent tuning is then used to modulate the partition coefficients (P) of triarylphosphines with 0-3 fluorous tags. The results lay a foundation for future applications of these and related biphasic systems in catalysis and extraction. © 2007 Elsevier Ltd. All rights reserved.
JF  - Tetrahedron
VL  - 63
SN  - 0040-4020
TI  - New fluorous/organic biphasic systems achieved by solvent tuning
SP  - 9890 
AV  - public
EP  -  9895
ER  -