relation: http://d-scholarship-dev.library.pitt.edu/18362/
title: New fluorous/organic biphasic systems achieved by solvent tuning
creator: Chu, Q
creator: Yu, MS
creator: Curran, DP
description: Miscibility tests between 60 pairs of fluorous and organic solvents have been performed, and a number of biphasic systems based on hydrofluoroether solvents have been identified. Mutual solubilities of a series of fluorous and organic solvents have been measured to ascertain the compositions of the biphasic systems. A qualitative solvent tuning strategy based on solvent polarity and fluorophilicity/phobicity is introduced. Solvent tuning is then used to modulate the partition coefficients (P) of triarylphosphines with 0-3 fluorous tags. The results lay a foundation for future applications of these and related biphasic systems in catalysis and extraction. © 2007 Elsevier Ltd. All rights reserved.
date: 2007-09-24
type: Article
type: PeerReviewed
format: text/plain
language: en
rights: attached
identifier: http://d-scholarship-dev.library.pitt.edu/18362/1/licence.txt
identifier:   Chu, Q and Yu, MS and Curran, DP  (2007) New fluorous/organic biphasic systems achieved by solvent tuning.  Tetrahedron, 63 (39).  9890 - 9895.  ISSN 0040-4020     
relation: 10.1016/j.tet.2007.06.092