%A T Tonoi
%A W Zhang
%A DP Curran
%A K Mikami
%J Chirality
%T Fluorous "racemic" mixture synthesis: Polysaccharide-based chiral columns for simultaneous demix and enantioseparation of racemic fluorous tagged compounds
%X The proof of concept experiments of fluorous "racemic" mixture synthesis (FRMS) is shown using polysaccharide-based chiral stationary phases. The mixture of racemic O-benzoylmandelate derivatives bearing different lengths of fluorous cleavable tags undergoes sequential reactions to provide individual derivatives as well as their enantiomers resolved on polysaccharide-based chiral HPLC columns (DAICEL CHIRALCEL? and CHIRALPAK? series). ? 2008 Wiley-Liss, Inc.
%N 3-4
%P 597 - 603
%V 20
%D 2008
%R 10.1002/chir.20487
%L pittir18119