%0 Journal Article
%@ 0899-0042
%A Tonoi, T
%A Zhang, W
%A Curran, DP
%A Mikami, K
%D 2008
%F pittir:18119
%J Chirality
%N 3-4
%P 597 - 603
%T Fluorous "racemic" mixture synthesis: Polysaccharide-based chiral columns for simultaneous demix and enantioseparation of racemic fluorous tagged compounds
%U http://d-scholarship-dev.library.pitt.edu/18119/
%V 20
%X The proof of concept experiments of fluorous "racemic" mixture synthesis (FRMS) is shown using polysaccharide-based chiral stationary phases. The mixture of racemic O-benzoylmandelate derivatives bearing different lengths of fluorous cleavable tags undergoes sequential reactions to provide individual derivatives as well as their enantiomers resolved on polysaccharide-based chiral HPLC columns (DAICEL CHIRALCEL® and CHIRALPAK® series). © 2008 Wiley-Liss, Inc.