relation: http://d-scholarship-dev.library.pitt.edu/18101/
title: Confirmation of the stereostructure of (+)-cytostatin by fluorous mixture synthesis of four candidate stereoisomers
creator: Jung, WH
creator: Guyenne, S
creator: Riesco-Fagundo, C
creator: Mancuso, J
creator: Nakamura, S
creator: Curran, DP
description: Mix and match: Four closely related candidate isomers for cytostatin have been synthesized by using the technique of fluorous mixture synthesis. Comparison of NMR, thin-layer chromatography, and optical rotation data enabled the three isomers that were not cytostatin to be identified. Thus, by a process of elimination (disproof), the isomer corresponding to cytostatin was determined, and the 4S,5S,6S,9S,10S,11S configuration confirmed. (Chemical Equation Presented). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
date: 2008-02-11
type: Article
type: PeerReviewed
format: text/plain
language: en
rights: attached
identifier: http://d-scholarship-dev.library.pitt.edu/18101/1/licence.txt
identifier:   Jung, WH and Guyenne, S and Riesco-Fagundo, C and Mancuso, J and Nakamura, S and Curran, DP  (2008) Confirmation of the stereostructure of (+)-cytostatin by fluorous mixture synthesis of four candidate stereoisomers.  Angewandte Chemie - International Edition, 47 (6).  1130 - 1133.  ISSN 1433-7851     
relation: 10.1002/anie.200704893