TY - JOUR ID - pittir18034 UR - http://d-scholarship-dev.library.pitt.edu/18034/ A1 - Jordan, KD A1 - Wang, F Y1 - 2003/09/23/ N2 - The problem of the binding of an excess electron to polar molecules and their clusters has long fascinated researchers. Although excess electrons bound to such species tend to be very extended spatially and to have little spatial overlap with the valence electrons of the neutral molecules, inclusion of electron correlation effects is essential for quantitatively describing the electron binding. The major electron correlation contribution may be viewed as a dispersion interaction between the excess electron and the electrons of the molecule or cluster. Recent work using a one-electron Drude model to describe excess electrons interacting with polar molecules is reviewed. JF - Annual Review of Physical Chemistry VL - 54 SN - 0066-426X TI - Theory of Dipole-Bound Anions SP - 367 AV - public EP - 396 ER -