@article{pittir17962, volume = {116}, number = {12}, month = {March}, author = {WH Robertson and K Karapetian and P Ayotte and KD Jordan and MA Johnson}, title = {Infrared predissociation spectroscopy of I{\ensuremath{<}}sup{\ensuremath{>}}-{\ensuremath{<}}/sup{\ensuremath{>}}?(CH{\ensuremath{<}}inf{\ensuremath{>}}3{\ensuremath{<}}/inf{\ensuremath{>}}OH){\ensuremath{<}}inf{\ensuremath{>}}n{\ensuremath{<}}/inf{\ensuremath{>}}, n = 1,2: Cooperativity in asymmetric solvation}, journal = {Journal of Chemical Physics}, pages = {4853 -- 4857}, year = {2002}, url = {http://d-scholarship-dev.library.pitt.edu/17962/}, abstract = {Infrared predissociation spectroscopy of I-?(CH3OH)n was studied. The spectra of the cold, argon-solvated clusters establish the coexistence of two isomeric forms of n=2 cluster, with the asymmetric isomer displaying a dramatic OH red-shift. It was observed that the strongly red-shifted band is suppressed, while the bands assigned to the more open form are enhanced.} }