eprintid: 17714
rev_number: 16
userid: 1418
dir: disk0/00/01/77/14
datestamp: 2013-03-14 14:12:37
lastmod: 2019-02-02 15:59:01
status_changed: 2013-03-14 14:12:37
type: article
metadata_visibility: show
item_issues_count: 0
eprint_status: archive
creators_name: Zhao, Q
creators_name: Curran, DP
creators_name: Malacria, M
creators_name: Fensterbank, L
creators_name: Goddard, JP
creators_name: Lacôte, E
creators_email: 
creators_email: curran@pitt.edu
creators_email: 
creators_email: 
creators_email: 
creators_email: 
creators_id: 
creators_id: CURRAN
creators_id: 
creators_id: 
creators_id: 
creators_id: 
title: N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes
ispublished: pub
divisions: sch_as_chemistry
full_text_status: public
abstract: Reducing alkenes to tears: Addition of structurally diverse N-heterocyclic carbenes (NHCs) to silicon allows the reduction of propargylic and styryl alcohols through an organocatalyzed silylation/direct hydride transfer tandem reaction (see scheme). Catalytic turnover is enabled by the switch to and from hypervalent silicon. This provides a new synthetic application of NHC-main group element complexes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
date: 2011-08-29
date_type: published
publication: Chemistry - A European Journal
volume: 17
number: 36
pagerange: 9911 - 9914
refereed: TRUE
issn: 0947-6539
id_number: 10.1002/chem.201101822
pmid: 21796697
citation:   Zhao, Q and Curran, DP and Malacria, M and Fensterbank, L and Goddard, JP and Lacôte, E  (2011) N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes.  Chemistry - A European Journal, 17 (36).  9911 - 9914.  ISSN 0947-6539     
document_url: http://d-scholarship-dev.library.pitt.edu/17714/1/licence.txt