TY  - JOUR
ID  - pittir17714
UR  - http://d-scholarship-dev.library.pitt.edu/17714/
IS  - 36
A1  - Zhao, Q
A1  - Curran, DP
A1  - Malacria, M
A1  - Fensterbank, L
A1  - Goddard, JP
A1  - Lacôte, E
Y1  - 2011/08/29/
N2  - Reducing alkenes to tears: Addition of structurally diverse N-heterocyclic carbenes (NHCs) to silicon allows the reduction of propargylic and styryl alcohols through an organocatalyzed silylation/direct hydride transfer tandem reaction (see scheme). Catalytic turnover is enabled by the switch to and from hypervalent silicon. This provides a new synthetic application of NHC-main group element complexes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
JF  - Chemistry - A European Journal
VL  - 17
SN  - 0947-6539
TI  - N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes
SP  - 9911 
AV  - public
EP  -  9914
ER  -