relation: http://d-scholarship-dev.library.pitt.edu/17714/
title: N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes
creator: Zhao, Q
creator: Curran, DP
creator: Malacria, M
creator: Fensterbank, L
creator: Goddard, JP
creator: Lacôte, E
description: Reducing alkenes to tears: Addition of structurally diverse N-heterocyclic carbenes (NHCs) to silicon allows the reduction of propargylic and styryl alcohols through an organocatalyzed silylation/direct hydride transfer tandem reaction (see scheme). Catalytic turnover is enabled by the switch to and from hypervalent silicon. This provides a new synthetic application of NHC-main group element complexes. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
date: 2011-08-29
type: Article
type: PeerReviewed
format: text/plain
language: en
rights: attached
identifier: http://d-scholarship-dev.library.pitt.edu/17714/1/licence.txt
identifier:   Zhao, Q and Curran, DP and Malacria, M and Fensterbank, L and Goddard, JP and Lacôte, E  (2011) N-heterocyclic carbene-catalyzed hydrosilylation of styryl and propargylic alcohols with dihydrosilanes.  Chemistry - A European Journal, 17 (36).  9911 - 9914.  ISSN 0947-6539     
relation: 10.1002/chem.201101822