eprintid: 17700
rev_number: 18
userid: 1418
dir: disk0/00/01/77/00
datestamp: 2013-03-14 14:11:45
lastmod: 2021-02-02 14:55:19
status_changed: 2013-03-14 14:11:45
type: article
metadata_visibility: show
item_issues_count: 0
eprint_status: archive
creators_name: Tehfe, MA
creators_name: Monot, J
creators_name: Malacria, M
creators_name: Fensterbank, L
creators_name: Fouassier, JP
creators_name: Curran, DP
creators_name: Lacôte, E
creators_name: Lalevée, J
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creators_email: curran@pitt.edu
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creators_id: CURRAN
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title: A water-compatible NHC-borane: Photopolymerizations in water and rate constants for elementary radical reactions
ispublished: pub
divisions: sch_as_chemistry
full_text_status: public
abstract: Rate constants for important elementary reactions of 2,4-dimethyl-1,2,4- triazol- 3-ylidene borane (1) and its derived boryl radical have been measured in the presence and absence of water. Reactions including H-abstraction by tBuO, and onward reactions of the derived radical with methyl acrylate (addition), iodopropane (halogen abstraction), and an iodonium salt (oxidation) are unaffected by the presence of a high concentration (1.5 M) of water. Extending these results, borane (1) has been found to be an efficient new co-initiator for the visible light photopolymerization of monomers in the presence of both air and water. © 2011 American Chemical Society.
date: 2012-01-17
date_type: published
publication: ACS Macro Letters
volume: 1
number: 1
pagerange: 92 - 95
refereed: TRUE
id_number: 10.1021/mz200087g
citation:   Tehfe, MA and Monot, J and Malacria, M and Fensterbank, L and Fouassier, JP and Curran, DP and Lacôte, E and Lalevée, J  (2012) A water-compatible NHC-borane: Photopolymerizations in water and rate constants for elementary radical reactions.  ACS Macro Letters, 1 (1).  92 - 95.      
document_url: http://d-scholarship-dev.library.pitt.edu/17700/1/licence.txt