TY  - JOUR
ID  - pittir17362
UR  - http://d-scholarship-dev.library.pitt.edu/17362/
IS  - 7-8
A1  - Sancho, AG
A1  - Wang, X
A1  - Sui, B
A1  - Curran, DP
Y1  - 2009/05/01/
N2  - The relative stabilities of two fluorous analogs, diisopropyl(3,3,4,4,5,5, 6,6,7,7,8,8,9,9,10,10,10-heptadecafluorodecyl)silyl and diisopropyl-(4,4,5,5,6, 6,7,7,8,8,9,9,10,10,11,11,11-heptadeca-fluoroundecyl)silyl [C8F 17(CH2)nSi(i-Pr)2, where n = 2 or 3], of the standard triisopropylsilyl (TIPS) group are compared in the setting of alcohol protection. The fluorous silyl groups can be installed under standard conditions in comparable yields to the TIPS group, but the derived fluorous silyl ethers are more labile than TIPS ethers towards cleavage by both acids and fluoride. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.
JF  - Advanced Synthesis and Catalysis
VL  - 351
SN  - 1615-4150
TI  - Comparison of the relative reactivities of the triisopropylsilyl group with two fluorous analogs
SP  - 1035 
AV  - public
EP  -  1040
ER  -