eprintid: 17240
rev_number: 26
userid: 1419
dir: disk0/00/01/72/40
datestamp: 2013-02-08 21:02:53
lastmod: 2021-06-12 23:55:33
status_changed: 2013-02-08 21:02:53
type: article
metadata_visibility: show
item_issues_count: 0
eprint_status: archive
creators_name: Yan, F
creators_name: Asher, S
creators_email: 
creators_email: asher@pitt.edu
creators_id: 
creators_id: ASHER
title: Cation identity dependence of crown ether photonic crystal Pb<sup>2+</sup> sensing
ispublished: pub
divisions: sch_as_chemistry
full_text_status: public
abstract: We quantitatively modeled the volume phase transition of a hydrogel containing a crystalline colloidal array with a crown ether ligand which binds Pb2+. The hydrogel volume response and the wavelength diffracted depend on the Pb2+ concentration and on both the ionic strength and the valence of the nonbinding ionic species. We successfully modeled the response of this hydrogel Pb2+ sensor to ionic strength and the cation valence of the added salts. [Figure not available: see fulltext.]. © Springer-Verlag 2007.
date: 2007-03-01
date_type: published
publication: Analytical and Bioanalytical Chemistry
volume: 387
number: 6
pagerange: 2121 - 2130
refereed: TRUE
issn: 1618-2642
id_number: 10.1007/s00216-006-1088-8
pmid: 17333156
mesh_headings: Cations, Divalent--chemistry
mesh_headings: Chromones
mesh_headings: Crown Ethers--chemistry
mesh_headings: Crystallization
mesh_headings: Lead--chemistry
mesh_headings: Osmolar Concentration
mesh_headings: Photochemistry
mesh_headings: Solutions
chemical_names: Cations, Divalent
chemical_names: Chromones
chemical_names: Crown Ethers
chemical_names: Solutions
chemical_names: 6-propylchromone-2-carboxylic acid
chemical_names: Lead
citation:   Yan, F and Asher, S  (2007) Cation identity dependence of crown ether photonic crystal Pb<sup>2+</sup> sensing.  Analytical and Bioanalytical Chemistry, 387 (6).  2121 - 2130.  ISSN 1618-2642     
document_url: http://d-scholarship-dev.library.pitt.edu/17240/1/licence.txt