%A F Yan %A S Asher %J Analytical and Bioanalytical Chemistry %T Cation identity dependence of crown ether photonic crystal Pb2+ sensing %X We quantitatively modeled the volume phase transition of a hydrogel containing a crystalline colloidal array with a crown ether ligand which binds Pb2+. The hydrogel volume response and the wavelength diffracted depend on the Pb2+ concentration and on both the ionic strength and the valence of the nonbinding ionic species. We successfully modeled the response of this hydrogel Pb2+ sensor to ionic strength and the cation valence of the added salts. [Figure not available: see fulltext.]. ? Springer-Verlag 2007. %N 6 %P 2121 - 2130 %V 387 %D 2007 %R 10.1007/s00216-006-1088-8 %L pittir17240