relation: http://d-scholarship-dev.library.pitt.edu/17237/
title: Generation and reactions of an unsubstituted n-heterocyclic carbene boryl anion
creator: Monot, J
creator: Solovyev, A
creator: Bonin-Dubarle, H
creator: Derat, E
creator: Curran, DP
creator: Robert, M
creator: Fensterbank, L
creator: Malacria, M
creator: Lacôte, E
description: Lying low: A lithiated unsubstituted N-heterocyclic carbene (NHC) boryl anion can be generated by reduction, and trapped by electrophiles (see scheme; dipp=2,6-diisopropylphenyl) to provide new substituted NHC boranes. It is yet another example of a low-valent boron compound or boron-containing reactive intermediate stabilized by an NHC, thereby extending the scope of NHC borane chemistry. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
date: 2010-11-22
type: Article
type: PeerReviewed
format: text/plain
language: en
rights: attached
identifier: http://d-scholarship-dev.library.pitt.edu/17237/1/licence.txt
identifier:   Monot, J and Solovyev, A and Bonin-Dubarle, H and Derat, E and Curran, DP and Robert, M and Fensterbank, L and Malacria, M and Lacôte, E  (2010) Generation and reactions of an unsubstituted n-heterocyclic carbene boryl anion.  Angewandte Chemie - International Edition, 49 (48).  9166 - 9169.  ISSN 1433-7851     
relation: 10.1002/anie.201004215