eprintid: 17148 rev_number: 19 userid: 1419 dir: disk0/00/01/71/48 datestamp: 2013-01-23 21:49:19 lastmod: 2019-02-02 16:55:07 status_changed: 2013-01-23 21:49:19 type: article metadata_visibility: show item_issues_count: 0 eprint_status: archive creators_name: Reese, CE creators_name: Asher, SA creators_email: creators_email: asher@pitt.edu creators_id: creators_id: ASHER title: Emulsifier-free emulsion polymerization produces highly charged, monodisperse particles for near infrared photonic crystals ispublished: pub divisions: sch_as_chemistry full_text_status: public abstract: We have developed emulsifier-free, emulsion polymerization recipes for the synthesis of highly charged, monodisperse latex particles of diameters between 500 and 1100 nm. These latexes consist of poly[styrene-(co-2-hydroxyethyl methacrylate)] spherical particles whose surfaces are functionalized with sulfate and carboxylic acid groups. These highly charged, monodisperse particles readily self-assemble into robust, three-dimensionally ordered crystalline colloidal array photonic crystals that Bragg diffract light in the near infrared spectral region. By altering the particle number density, the diffraction wavelength can be tuned from ∼1000 to ∼4000 nm. © 2002 Elsevier Science (USA). date: 2002-01-01 date_type: published publication: Journal of Colloid and Interface Science volume: 248 number: 1 pagerange: 41 - 46 refereed: TRUE issn: 0021-9797 id_number: 10.1006/jcis.2001.8193 pmid: 16290501 citation: Reese, CE and Asher, SA (2002) Emulsifier-free emulsion polymerization produces highly charged, monodisperse particles for near infrared photonic crystals. Journal of Colloid and Interface Science, 248 (1). 41 - 46. ISSN 0021-9797 document_url: http://d-scholarship-dev.library.pitt.edu/17148/1/licence.txt