eprintid: 16753
rev_number: 14
userid: 1587
dir: disk0/00/01/67/53
datestamp: 2013-01-25 16:56:34
lastmod: 2016-11-15 14:07:57
status_changed: 2013-01-25 16:56:34
type: thesis_degree
metadata_visibility: show
contact_email: buck.e.18@gmail.com
item_issues_id: duplicate_title_16742
item_issues_type: duplicate_title
item_issues_description: Duplicate title to <span class="person_name">Buck, Eric</span> <a href="http://d-scholarship.pitt.edu/cgi/users/home?screen=EPrint::View&amp;eprintid=16742"><xhtml:em xmlns:xhtml="http://www.w3.org/1999/xhtml">SYNTHETIC STUDIES TOWARDS THE SYNTHESIS OF ANATOXIN-A(S).</xhtml:em></a> Doctoral Dissertation, University of Pittsburgh.
item_issues_timestamp: 2012-12-05 07:15:37
item_issues_status: autoresolved
item_issues_count: 0
eprint_status: archive
creators_name: Buck, Eric
creators_email: eeb34@pitt.edu
creators_id: EEB34
title: SYNTHETIC STUDIES TOWARDS THE SYNTHESIS OF ANATOXIN-A(S)
ispublished: unpub
divisions: sch_as_chemistry
full_text_status: public
keywords: anatoxin-a(s), guanidine, 
abstract: Three routes toward the total synthesis of the neurotoxin anatoxin-a(s) have been explored. They focus on the assembly of the backbone utilizing both Pd(0)- and Pd(II)-mediated processes. Our current route leads to a late-stage precursor of anatoxin-a(s), hydroxy guanidine 134, in 18 steps and in 8.0% overall yield utilizing an amidoalkylation step in the key cyclization.
date: 2013-01-25
date_type: published
pages: 136
institution: University of Pittsburgh
refereed: TRUE
etdcommittee_type: committee_chair
etdcommittee_type: committee_member
etdcommittee_type: committee_member
etdcommittee_type: committee_member
etdcommittee_name: Wipf, Peter
etdcommittee_name: Koide, Kazunori
etdcommittee_name: Nelson, Scott
etdcommittee_name: Day, Billy W
etdcommittee_email: pwipf@pitt.edu
etdcommittee_email: koide@pitt.edu
etdcommittee_email: sgnelson@pitt.edu
etdcommittee_email: bday@pitt.edu
etdcommittee_id: PWIPF
etdcommittee_id: KOIDE
etdcommittee_id: SGNELSON
etdcommittee_id: BDAY
etd_defense_date: 2012-11-29
etd_approval_date: 2013-01-25
etd_submission_date: 2012-12-04
etd_release_date: 2013-01-25
etd_access_restriction: immediate
etd_patent_pending: FALSE
thesis_type: dissertation
degree: PhD
citation:   Buck, Eric  (2013) SYNTHETIC STUDIES TOWARDS THE SYNTHESIS OF ANATOXIN-A(S).  Doctoral Dissertation, University of Pittsburgh.    (Unpublished)  
document_url: http://d-scholarship-dev.library.pitt.edu/16753/1/Buck-Thesis.pdf