eprintid: 16289
rev_number: 16
userid: 1418
dir: disk0/00/01/62/89
datestamp: 2012-11-15 21:22:32
lastmod: 2019-02-02 15:58:31
status_changed: 2012-11-15 21:22:32
type: article
metadata_visibility: show
item_issues_id: similar_title_37134
item_issues_type: similar_title
item_issues_description: Similar title to 


    <span class="person_name">Bolt, Daniel</span>
  

(2019)

<a href="http://d-scholarship.pitt.edu/cgi/users/home?screen=EPrint::View&amp;eprintid=37134"><xhtml:em xmlns:xhtml="http://www.w3.org/1999/xhtml">Synthesis and Reactions N-Heterocyclic Carbene Boranes.</xhtml:em></a>


    Doctoral Dissertation, University of Pittsburgh.
  


   (Unpublished)
item_issues_timestamp: 2019-07-19 06:02:02
item_issues_status: discovered
item_issues_count: 1
eprint_status: archive
creators_name: Curran, DP
creators_name: Solovyev, A
creators_name: Makhlouf Brahmi, M
creators_name: Fensterbank, L
creators_name: Malacria, M
creators_name: Lacôte, E
creators_email: curran@pitt.edu
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creators_email: 
creators_id: CURRAN
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title: Synthesis and reactions of N-heterocyclic carbene boranes
ispublished: pub
divisions: sch_as_chemistry
full_text_status: public
abstract: Boranes are widely used Lewis acids and N-heterocyclic carbenes (NHCs) are popular Lewis bases, so it is remarkable how little was known about their derived complexes until recently. NHC-boranes are typically readily accessible and many are so stable that they can be treated like organic compounds rather than complexes. They do not exhibit "borane chemistry", but instead are proving to have a rich chemistry of their own as reactants, as reagents, as initiators, and as catalysts. They have significant potential for use in organic synthesis and in polymer chemistry. They can be used to easily make unusual complexes with a broad spectrum of functional groups not usually seen in organoboron chemistry. Many of their reactions occur through new classes of reactive intermediates including borenium cations, boryl radicals, and even boryl anions. This Review provides comprehensive coverage of the synthesis, characterization, and reactions of NHC-boranes. Forget everything you know about boron chemistry ... NHC-boranes (see picture) are different. Functionalities that are not usually present in organoboron compounds can be easily introduced. New classes of rare boron-based reactive intermediates (cations, radicals, and anions) have emerged. And NHC-boranes are promising as reagents and catalysts in organic synthesis and as co-initiators in radical polymerization. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
date: 2011-10-24
date_type: published
publication: Angewandte Chemie - International Edition
volume: 50
number: 44
pagerange: 10294 - 10317
refereed: TRUE
issn: 1433-7851
id_number: 10.1002/anie.201102717
article_type: review
pmid: 21898724
citation:   Curran, DP and Solovyev, A and Makhlouf Brahmi, M and Fensterbank, L and Malacria, M and Lacôte, E  (2011) Synthesis and reactions of N-heterocyclic carbene boranes.  Angewandte Chemie - International Edition, 50 (44).  10294 - 10317.  ISSN 1433-7851     
document_url: http://d-scholarship-dev.library.pitt.edu/16289/1/licence.txt