@article{pittir16188,
          volume = {133},
          number = {50},
           month = {December},
          author = {R Bajpai and DP Curran},
           title = {Synthesis and spectroscopic analysis of a stereoisomer library of the phytophthora mating hormone {\ensuremath{\alpha}}1 and derived bis-Mosher esters},
         journal = {Journal of the American Chemical Society},
           pages = {20435 -- 20443},
            year = {2011},
             url = {http://d-scholarship-dev.library.pitt.edu/16188/},
        abstract = {Fluorous mixture synthesis provided all eight diastereomers of the phytophthora hormone {\ensuremath{\alpha}}1 with the R configuration at C11 as individual samples after demixing and detagging. The library of all possible bis-Mosher esters (16) was then made by esterification. Complete sets of 1H, 13C, and (for the Mosher esters) 19F NMR spectra were recorded, assigned, and compared with each other and with published spectra. Not all of the spectra are unique, and the 1H NMR spectra of the Mosher esters provided the most information. The previous assignment of the natural sample as an "all-R" stereoisomer mixed with its 3S-epimer was confirmed. {\copyright} 2011 American Chemical Society.}
}