TY  - JOUR
ID  - pittir16159
UR  - http://d-scholarship-dev.library.pitt.edu/16159/
IS  - 5963
A1  - Relph, RA
A1  - Guaseo, TL
A1  - Elliott, BM
A1  - Kamrath, MZ
A1  - McCoy, AB
A1  - Steele, RP
A1  - Schofield, DP
A1  - Jordan, KD
A1  - Viggiano, AA
A1  - Ferguson, EE
A1  - Johnson, MA
Y1  - 2010/01/15/
N2  - Many chemical reactions in atmospheric aerosols and bulk aqueous environments are influenced by the surrounding solvation shell, but the precise molecular interactions underlying such effects have rarely been elucidated. We exploited recent advances in isomer-specific cluster vibrational spectroscopy to explore the fundamental relation between the hydrogen (H)-bonding arrangement of a set of ion-solvating water molecules and the chemical activity of this ensemble. We find that the extent to which the nitrosonium ion (NO+) and water form nitrous acid (HONO) and a hydrated proton cluster in the critical trihydrate depends sensitively on the geometrical arrangement of the water molecules in the network. Theoretical analysis of these data details the role of the water network in promoting charge derealization.
JF  - Science
VL  - 327
SN  - 0036-8075
TI  - How the shape of an H-Bonded network controls proton-coupled water activation in HONO formation
SP  - 308 
AV  - public
EP  -  312
ER  -