TY  - JOUR
ID  - pittir16070
UR  - http://d-scholarship-dev.library.pitt.edu/16070/
IS  - 21
A1  - Clarkson, JR
A1  - Dian, BC
A1  - Moriggi, L
A1  - Defusco, A
A1  - McCarthy, V
A1  - Jordan, KD
A1  - Zwier, TS
Y1  - 2005/06/01/
N2  - The methods of stimulated emission pumping-hole spectroscopy (SEP-HFS) and stimulated emission pumping population transfer spectroscopy (SEP-PTS) were applied to the conformation-specific study of conformational isomerization in tryptamine. The methods employ stimulated emission pumping to selectively excite a fraction of the population of a single conformation of TRA to well-defined ground-state vibration levels. The method uses collisions as an integral part of the experimental scheme. Hole-filling methods can also be applied to the study of isomerization in a much wider range of contexts.
JF  - Journal of Chemical Physics
VL  - 122
SN  - 0021-9606
TI  - Direct measurement of the energy thresholds to conformational isomerization in Tryptamine: Experiment and theory
AV  - public
ER  -